加成法合成氨基硅油  

Preparation of amino-silicone by hydrosilyation reaction

作　　者：郑帼[1] 刘燕军[1] 葛启[1] 

机构地区：[1]天津工业大学精细化工研究所,天津300160

出　　处：《纺织学报》2005年第1期73-75,共3页Journal of Textile Research

摘　　要：以H2 PtCl6 为催化剂 ,以丙烯胺与含氢硅油加成 ,合成了氨值在 0 8～ 1 5的侧基型氨基硅油 ,并且在硅油分子中引入了烷氧基。最佳的反应条件是以甲苯为溶剂 ,催化剂用量 0 2mmol g,回流条件下在 2h内滴加丙烯胺 ,继续保温 2～ 3h ,然后在 30min内加入正丙醇 ,继续反应 90min。The amino-silicone was prepared by hydrosilylation of hydrogen-silicone with a llyl amino.The amino-value of the amino-sili cone is 0.8～1.5, and then inserted the alkoxy group into the structure to imp rove the crosslink ability.The optimal reactive condition was the toluene as sol vent,H 2PtCl 6 catalyst content 0.2 mmol/g and added the allyl amino to hyd rogen-silicone dropwise within 2 hours under reflux.Kept the temperature to r ea ct 2～3 h,then added n-propanol containing KOH in 30 minutes and reacted 90 m inutes to gain amino-silicone containing alkoxy group.

关 键 词：氨基硅油 加成法 含氢硅油 柔软剂 

分 类 号：TS103.841[轻工技术与工程—纺织工程]