丙烯酸/环氧树脂接枝共聚物及其水性涂料  

EPOXY-ACRYLATE GRAFTED POLYMER AND ITS WATER BORNE PAINT

作　　者：杨勋兰[1] 孙绍晖[1] 孙培勤[1] 刘大壮[1] 

机构地区：[1]郑州大学工学院化工学院,郑州450002

出　　处：《热固性树脂》2005年第1期9-11,共3页Thermosetting Resin

基　　金：河南省攻关项目(0224380039)

摘　　要：通过丙烯酸类单体与环氧树脂接枝共聚反应,在环氧树脂中引入强亲水性基团—COOH,使树脂水性化。研究了环氧树脂分子质量、单体种类、溶剂及反应条件对接枝共聚物水分散稳定性的影响,并考查了漆膜的固化条件。所得涂膜附着力、柔韧性、耐水性很好,可用作罐头内壁涂料和防腐涂料。Epoxy resin was modified by graft copolymerization with acrylate monomers and the strong hydrophilic group—COOH was interlinked in chain.The waterborne epoxy-acrylate emulsion was synthesized.The factors affecting the emulsion stability,such as molecular weight of epoxy resin,nonomers,solvents and the reaction conditions were also studied.The conditions of cure were studied too.The film coating had good adhesion,flexibility and resistance to water.

关 键 词：环氧树脂 丙烯酸 接枝 水性涂料 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]