Synthesis and Crystal Structure of Zinc Complex [Zn(bipy)_3][Zn(SCN)_4]  

作　　者：何翔 卢灿忠 张全争 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China

出　　处：《Chinese Journal of Structural Chemistry》2005年第2期159-162,共4页结构化学（英文）

基　　金：This work was supported by 973 Program of the MOST (001CB108906); the NNSFC (90206040; 20073048 20333070 and 20303021);NSF of Fujian Province (2002F015 and 2002J006);the Chinese Academy of Sciences

摘　　要：The hydrothermal reaction of thiocyanate, 2,2?-bipyridine and ZnII in basified aqueous solutions gave rise to complex [Zn(bipy)3][Zn(SCN)4] 1 (C34H24N10S4Zn2) which was characterized by X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, Mr= 831.61, Z = 4, a = 15.920(3), b = 13.5201(17), c = 17.362(3) ?, β = 99.467(9)o, V = 3686.1(10) ?3, Dc = 1.499 g/cm3, μ = 1.568 mm-1, F(000) = 1688, R = 0.0586 and wR = 0.1354 for 5604 observed reflections (I > 2σ(I)). The photoluminescence spectrum for the title compound has also been studied.The hydrothermal reaction of thiocyanate, 2,2?-bipyridine and ZnII in basified aqueous solutions gave rise to complex [Zn(bipy)3][Zn(SCN)4] 1 (C34H24N10S4Zn2) which was characterized by X-ray diffraction analysis. Crystal data for 1: monoclinic, space group P21/n, Mr= 831.61, Z = 4, a = 15.920(3), b = 13.5201(17), c = 17.362(3) ?, β = 99.467(9)o, V = 3686.1(10) ?3, Dc = 1.499 g/cm3, μ = 1.568 mm-1, F(000) = 1688, R = 0.0586 and wR = 0.1354 for 5604 observed reflections (I > 2σ(I)). The photoluminescence spectrum for the title compound has also been studied.

关 键 词：ZINC THIOCYANATE crystal structure PHOTOLUMINESCENCE 

分 类 号：O614.241[理学—无机化学] TN104.3[理学—化学]