5,10,15,20-四(对-乙酯苯基)卟啉LB膜的结构  

ON THE STRUCTURE OF LB FILM OF 5,10,15,20-TETRA(p-ETHOXYCARBONPHENYL)PORPHYRIN

作　　者：王海水[1] 周宇清[1] 金日镇[1] 席时权[1] 

机构地区：[1]中国科学院长春应用化学研究所,长春130022

出　　处：《应用化学》1993年第2期87-88,共2页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金

摘　　要：对卟啉类化合物LB膜的结构、电性质和气敏性的研究已见报道。本文利用膜天平和UV-Vis分光光度计研究了标题化合物在气-液界面上的成膜特性、分子间相互作用和LB膜的结构。5,10,15,20-四（对-乙酯苯基）卟啉（TPEPP）由5,10,15,20-四（对-氰苯基）卟啉和乙醇酯化得到。元素分析测定值与计算值相符。λ（CHCl₃,nm）:421,515,550,590,645;The composition and structure of the title compound are verified by elemental analysis,UVVis and IR spectra. It forms a well-behaved monomolecular layer at the air-water interface. The surface pressure-molecular area isotherms depend on the pre-treatment. The UV-Vis spectra of the LB film indicate that molecular interaction come mainly from the same layer. Polarized UV-Vis spectra show that the porphyrin rings in the LB film are tilted to the film plane.

关 键 词：卟啉 LB膜 结构 

分 类 号：O484.1[理学—固体物理]