蒽、苝和1-氨基蒽醌水溶胶的制备及其荧光性能的研究  

Preparation and Fluorescence Study of Anthracene, Perylene and 1-Aminoanthraquinone Colloids

作　　者：刘金水[1] 李永新[1] 高峰[1] 王伦[1] 

机构地区：[1]安徽师范大学化学与材料科学学院,安徽芜湖241000

出　　处：《光谱学与光谱分析》2005年第1期76-78,共3页Spectroscopy and Spectral Analysis

基　　金：安徽师大校青年基金(2003×9A12);国家自然科学基金(20375001)资助项目

摘　　要：用再沉淀法分别制备了蒽、和1氨基蒽醌水溶胶,研究了三者在水溶液中的荧光光谱,通过与其对应的分子荧光光谱比较,发现蒽和的水溶胶荧光光谱发生了红移,而1氨基蒽醌分子从无荧光到它的水溶胶有荧光的转变,根据荧光和分子结构关系,得出3种溶胶是通过分子之间相互重叠聚集而成。同时因为他们为平面型分子,因此π电子共轭度大,使得荧光容易激发和发射,荧光光谱向长波方向移动。Anthracene, perylene and 1-aminoanthraquinone colloids have been prepared by reprecipitation method. In comparison with the fluorescence emission spectra of colloids and molecules (in acetone solution), it was indicated that collids fluorescence spectra are red-shifted and easy emission. Base on the fluorescence emission and molecular structure theory, the authors conclude that these molecules overlap when they form particles. At the same time they are planar molecules. This results in the strong stacking electronic properties. So fluorescence excitation and emission become easy.

关 键 词：荧光光谱 荧光性能 氨基 分子 共轭 蒽醌 电子 水溶胶 制备 沉淀法 

分 类 号：O626[理学—有机化学]