近年来国内高碳烯烃氢甲酰化反应研究进展  

National Research Development on High-Carbon Number Olefin Hydroformylation Reaction in Recent Years

作　　者：宋金波[1] 叶春林[1] 罗杨[1] 卞峰[1] 张燕飞[1] 

机构地区：[1]胜利油田采油工艺研究院,山东东营257061

出　　处：《山东化工》2004年第6期16-18,5,共4页Shandong Chemical Industry

摘　　要：介绍了近年来国内高碳烯烃氢甲酰化反应研究与开发进展 ,内容涉及高碳烯烃氢甲酰化反应的三个主要催化体系 :均相催化体系、水 /有机两相催化体系、固载水相催化体系。国内近年来研究进展表明 ,尽管运用三个主要催化体系所进行的研究取得一定进展 ,但就各个催化体系的不同特点 ,又都面临一些亟待解决的问题 ,实现反应的工业化尚待时日。This article mainly introduces national research and development on high-carbon number olefin hydroformylation reaction in recent years.The content involves three important reaction systems(such as biphasic catalytic system,homogeneous catalytic system) of olefin hydroformylation,the research shows:according to the characteristic of respective reaction system,there stil have some formidable problems to be resolved,thought different achivement have been gained in respective reaction system.The goal of realizing industrialization needs further study.

关 键 词：高碳烯烃 氢甲酰化 水溶性膦配体 水/有机两相催化 均相催化体系 

分 类 号：TQ203.2[化学工程—有机化工] TQ223.12