可溶性氧钒酞菁的合成及取代基位置对其性质的影响  

Syntheses of Soluble Vanadyl Phthalocyanines and the Effect of Substituting Positions on Phthalocyanine's Properties

作　　者：邱玲[1] 沈玉全[1] 许慧君[1] 沈继峰 傅兴发 

机构地区：[1]中国科学院感光化学研究所,北京100101

出　　处：《有机化学》1993年第5期490-495,共6页Chinese Journal of Organic Chemistry

摘　　要：酞菁化合物是一类热稳定性和化学稳定性都很高的化合物,由于具有良好的耐热、耐晒、耐酸碱及色泽鲜艳等性能,已被广泛地应用于颜料、染料及印染工业。另外,酞菁作为催化剂,特别是作为光导、二维有机导体、光电材料和三阶非线性光学材料等的研究,也越来越引起人们的兴趣。研究酞菁的上述性质时。Soluble 1, 8, 15, 22-and 2, 9, 16, 23-tetraalkylamide vanadyl phthalocyanines(1 and 2)were synthesized and their spectrum properties were investigated. The two phthalocyanine com-pounds exist in different forms in solutions and in PMMA films. It was also found that the Q bandof 1 has a bathochromic shift of 47nm relative to that of 2, therefore it may pfovide a new way forshifting the Q bands of phthalocyanines bathochromically by the substitution pattern similar to 1.

关 键 词：氧钒酞菁 合成 取代基位置 

分 类 号：O627.53[理学—有机化学]