脂肪族方酰胺多齿配体的合成  

Synthesis of Multidentate Ligands Derived from Squaric Acid and Aliphatic Amines

作　　者：付家胜[1] 袁德其[2] 肖森[2] 谢如刚[2] 赵华明[2] 

机构地区：[1]泸州医学院化学教研室,四川泸州646000 [2]四川大学化学系,四川成都610064

出　　处：《有机化学》1993年第5期540-545,共6页Chinese Journal of Organic Chemistry

基　　金：国家教委博士点基金

摘　　要：近年来,对方酸的配位性能已有不少研究报道,但对方酰胺多齿配体的研究却不多见。我们曾合成并研究了以1,3-双苯氨基方酸内鎓盐为骨架,在苯环的2-位对称引人多甘醇醚链的双臂型方酰胺多齿配体,其中某些化合物既能作为配体对UO22+及This paper deals with the synthesis of a series of new multidentate ligands consisting ofthe 1, 3-bis (aliphatic amino) squaraine structure, which would be difficult to be obtained fromthe reaction of squaric acid and aliphatic amines. The title compounds were obtained byreacting 1, 3-bis (nitroanilino) squaraine with N-oligoethylene glycol (ether) substituted eth-anolamines or amino schiff′s bases 2 generated from the reaction of corresponding chloridesor salicyl aldehyde with appropriate amines.

关 键 词：脂肪族方酰胺 多齿配体 

分 类 号：O641.3[理学—物理化学]