新型尾式金属卟啉配合物的合成和表征  

The Synthesis and Characterization of a New Tailed Metalloporphyrin Coordination Compound

作　　者：计亮年[1] 覃夏[1] 黄锦汪[1] 

机构地区：[1]中山大学化学系/南京大学配位化学国家重点实验室

出　　处：《中山大学学报（自然科学版）》1993年第2期1-7,共7页Acta Scientiarum Naturalium Universitatis Sunyatseni

基　　金：国家自然科学基金

摘　　要：本文探讨了一种新型尾式卟啉5-对(4-(间-吡啶氧基)丁氧基]苯基-10,15,20三苯基卟啉(简称PyBPTPP)的合成路线,并以PyBPTPP 为配体合成了金属铁卟啉Fe(Ⅲ)PyBPTPPCl.通过元素分析、质谱、红外光谱、紫外可见光谱、核磁共振谱和热分忻等手段对上述化合物进行了表征.A new tailed porphyrin which bears covalently attached a pyridine as aaxial ligand,5-[4-(m-pyridyloxy) butoxy] pheny1-10,15,20-triphenylporphyrin(PyBPTPP)and its iron coordination compound (FePyBPTPPCl) have been synthesizedand characterized by elementary analysis,mass spectra,ultraviolet and vissiblespectra,infrared spectra,proton nuclear magnetic resonance spectra,thermo-gravimetic analysis and differential thermal analysis.The synthetic routes of thisnew tailed porphyrin were also discussed

关 键 词：尾式卟啉 金属卟啉 络合物 合成 

分 类 号：O641.4[理学—物理化学]