三乙醇胺催化下的反常Reimer－Tiemann反应  

The Behavior of Reimer-Tiemann Reaction Under the catalysis of Trietholamine

作　　者：严卫东 宣平[1] 杨家祥[1] 

机构地区：[1]安徽省合成材料研究所,安徽大学化学系

出　　处：《安徽大学学报（自然科学版）》1994年第2期66-69,共4页Journal of Anhui University(Natural Science Edition)

摘　　要：本文对三乙醇胺作相转移催化剂存在下的Ｒｅｉｍｅｒ—Ｔｉｅｍａｎｎ（以下简称Ｒ—Ｔ）反应进行了研究，结果表明，三乙醇胺对此反应有明显的影响，对位和邻位产物的产率是反常的。在此催化剂存在下的反常Ｒ—Ｔ反应未见报道。Reimer-Tiemann reaction umder phase transfer catalysis of trietholamine has been studied in this poper. It has been shown that trietholamine have an obvious catalytic effect on the reaction and that the ratio of para-and ortho-products is abnormal. Abnormal R-T reaction hasnot been reported under this catalysis in literature.

关 键 词：三乙醇胺 相转移催化剂 R-T反应 

分 类 号：O621.25[理学—有机化学]