卟啉化合物的合成及其对细胞色素P－450的模拟──XⅢ．PVC和CPVC固载TPPMn（Ⅲ）OH的合成及其对惰性氢键的温和催化活化  

SYNTHESIS OF PORPHYBIN COMPOUNDS AND THEIR IMITATION OF CYTOCHROME P-450 MONO-OXYGENASE──XIII.STUDY ON SYNTHESIS OF PVC AND CPVC SUPPORTED TPPMn(Ⅲ)OH AND MODERATE CATALYTIC ACTIVATION FOR INERT C-H BOND

作　　者：俞善信[1] 钟为标 郭灿城[1] 

机构地区：[1]湖南师范大学化学系,湖南大学化学化工系

出　　处：《Chinese Journal of Catalysis》1994年第3期232-235,共4页催化学报（英文）

基　　金：国家自然科学基金

摘　　要：卟啉化合物的合成及其对细胞色素Ｐ－４５０的模拟──ＸⅢ．ＰＶＣ和ＣＰＶＣ固载ＴＰＰＭｎ（Ⅲ）ＯＨ的合成及其对惰性氢键的温和催化活化俞善信，钟为标，郭灿城（湖南师范大学化学系，长沙４１００８１）（湖南大学化学化工系，长沙４１００８２）关键词高聚物，四苯...VC-and CPVC-bonded tetraphenylmanganese(Ⅲ) porphyrin complexes have been synthesized.It is shown that the polymer-bonded metalloporphyrins are effective catalysts for oxidation of cyclohexane to cyclohexanol and cyclohexanone under moderate condition.The supported manganese porphyrins as catalysts can be used repeatedly.

关 键 词：高聚物 锰 固载化 细胞色素 

分 类 号：O626.13[理学—有机化学]