氯化铁酸性溶液升温水解中相转化规律  

The Rules of Phase-Transformation on the Hydrolysis of Acidic Ferric Chloride Solution

作　　者：张玉亭[1] 于洺[1] 

机构地区：[1]天津纺织工学院纺化系

出　　处：《纺织基础科学学报》1994年第1期5-9,4,共6页

基　　金：国家自然科学基金

摘　　要：氯化铁酸性溶液升温强迫水解，生成细小的短纺棰形β－ＦｅＯＯＨ粒子，成长为棒状β－ＦｅＯＯＨ大粒子和发生相转化而生成球状或立方体α－Ｆｅ２Ｏ３粒子，相转化方式有三种：聚集再结晶式，交点膨胀式和独立成核武，其决定因素是原始陈化液中三价铁离子和氯离子的浓度。The hydrolyds of ferric chloride acidic solution at elevated temperyture is consisted of the formation of tiny spindle-shaped β-FeOOH particles, followed by the growing into large rodlike β-FeOOH particles and then phase-transforming into spheric or cubic α-Fe2O3. There are three type of phsae-transformations: Coagulation-recristallization, intersection-point expansion and indeependent nucleation. The determine factor is the concentrstion of ferric and chloride ions.

关 键 词：水解 相转化 氯化铁 溶液 胶体粒子 

分 类 号：O648[理学—物理化学]