环状低聚芳醚酮、聚芳醚砜和聚芳香酯的快离子轰击质谱分析  

Fast Ion Bombardment Mass Spectrometric Determination of Cyclic Oligomer Distributions in Polyaryletherketone, Polyarylethersulfone and Polyarylester

作　　者：郭兴华[1] 徐红华[1] 孙跃泉[1] 陈天禄[1] 刘淑莹[1] 

机构地区：[1]中国科学院长春应用化学研究所,长春130022

出　　处：《分析化学》1994年第9期873-876,共4页Chinese Journal of Analytical Chemistry

摘　　要：本文采用快离子轰击质谱(FIBMS)技术分别选用甘油、S-甘油和间硝基苄醇做底物,对五种环状芳香低聚物进行分析,确定了几种不同大小的芳香环状低聚物的存在,并同时给出了各种不同聚合度组分的相对含量.实验证明,质谱是分析环状低聚物的快速、有效的方法.Fast ion bombardment mass spectrometry (FIBMS) was used to identify cyclic oligomers containing aromatic rings produced in polycondensation reactions of poly aryletherketone, polyarylethersulfone and two polyarylesters using glycerol, thio-glycerol and 3-nitrobenzyl alcohol (3-NBA) as matrixes, respectively. The existence of different size (n value) cyclic oiigomcrs and their distributions were determined. The results indicated that the FIBMS was a powerful and rapid analytical method for the cyclic oligomers.

关 键 词：FIBMS 聚芳醚酮 聚芳醚砜 

分 类 号：O657.6[理学—分析化学]