高温煤焦油抽提物的色谱-质谱联用分析  

Analysis of Extract of High-temperature Coal Tar by Combined Capillary Gas Chromatography-Mass Spectrometry

作　　者：罗坚[1] 张秋花[1] 吴家珍 

机构地区：[1]湘潭矿业学院化工系,湘潭411201

出　　处：《分析化学》1994年第12期1248-1251,共4页Chinese Journal of Analytical Chemistry

基　　金：煤炭部优秀青年基金资助项目

摘　　要：以50m×0.25mm交联石英毛细管OV-1柱色质联用分析高温煤焦油的环己烷-乙醚抽提物,鉴定出200余组分,其中稠环芳烃144个,含氮、氧、硫的芳烃分别为39、7和8个。观察到5个未见报道的氮杂芳烃组分,首次同时检测分子量为240(M240)的四个含-CH_2-的异构体,并观察到了分子量高达316～332的芳烃。More than 200 components of high-temperature coal tar were detected,and identified on a HP-5980 GC/MS system with a 50 m×0. 25 mm crossklinked quartz OV-1 column, including 7 single ring aromatics, 144 polynuclear aromatics(PNAs),39 containing nitrogen PNAs, 7 containing oxygen-PNAs and 8 containing su1phur-PNAs. Indylcyanide, 2 isomers of dihydrodibenzoacridine and 2 isomers of aza-methy1cyclopenta[cd]pyrene were identified to be coal tar components. The whole 4 methylenebearing isomers of PNAs with molecular weight of 240 were found to coexist in the coal tar. PNAs with molecular weight up to 316-332 were observed, and tentatively identified.

关 键 词：色谱-质谱联用 稠环芳烃 煤焦油 

分 类 号：O657.6[理学—分析化学] TQ522.64[理学—化学]