应用FTIR光谱研究不同取代苯胺对O－乙基－N－异丙基（取代硫脲基）硫代磷酰胺酯生成反应的影响  

Application of FTIR Spectra to Study on the Influence of Various Substituted-Aniline on the Synthesis Reaction of O-Ethyl-isopropyl(substituted thiourea) thiophosphorylamidate

作　　者：何兰龄 赖城明[1] 林林[1] 徐谨民[1] 王永泰[1] 杨华铮[1] 吴烨[1] 

机构地区：[1]南开大学化学系,南开大学中心实验室,南开大学元素有机化学研究所

出　　处：《高等学校化学学报》1994年第3期398-400,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：应用ＦＴＩＲ光谱研究不同取代苯胺对Ｏ－乙基－Ｎ－异丙基（取代硫脲基）硫代磷酰胺酯生成反应的影响何兰龄，赖城明，林，徐谨民，王永泰，杨华铮，吴烨（南开大学化学系，天津，３０００７１）（南开大学中心实验室）（南开大学元素有机化学研究所）关键词ＦＴＩＲ，取...In this paper, the influence of substituent on the addition reaction of substitued aniline to O-ethyl-N-isopropyl(isothiocyano)thiophosphoramidate was studied, the relationship between rate constants and substituent constants is in accordance with Hammett relationship in our research region, and the reaction has been further discussed by means of MNDO calculation.

关 键 词：乙基 异丙基 硫代磷酰胺酯 萃胺 

分 类 号：O627.51[理学—有机化学]