脂溶性金属酞菁的合成及其作为PVC膜电极载体的研究  

Synthesis of Lipophilic Metal Phthalocyanines and Application for Carriers of PVC Membrane Electrode

作　　者：李俊忠[1] 庞新宇[1] 陆素 高德[1] 俞汝勤[1] 

机构地区：[1]湖南大学化学化工系

出　　处：《高等学校化学学报》1994年第11期1623-1625,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金;中国科学院长春应用化学研究所电分析化学开放实验室资助

摘　　要：脂溶性金属酞菁的合成及其作为ＰＶＣ膜电极载体的研究李俊忠，庞新宇，陆素，高德，俞汝勤（湖南大学化学化工系，长沙，４１００８２）关键词脂溶性金属酞菁，载体，ＰＶＣ膜电极金属酞菁由于价廉、稳定及其所具有的氧化还原性、光导电和催化等独特的物理化学性质，已在...Lipophilic 4,4',4',4-tetra-tert-butylphthalocyanine cobalt(Ⅱ) and copper(Ⅱ)were synthesized using 4-tert-butylphthalic acid as the starting material.The followingproducts were ascertained through elemental analysis, IR and UV/Vis spectra.Thelipophilic compounds were used as carriers of PVC membrane electrode, and it was foundthat the PVC membrane electrode based on 4,4',4',4-tetra-tert-butylphthalocyanine cobaltresponsed linearly to nitrite in a wide range with a high selectivety toward nitrite under theconditions.

关 键 词：脂溶性酞菁 PVC膜电极 载体 

分 类 号：TQ613.5[化学工程—精细化工]