氯化聚乙烯双亲性接枝聚合物的合成与表征（Ⅰ）  

SYTHESIS AND OF DOUBLE AFFINITYGRAFT POLYMER OF CPE

作　　者：杨启彪 杨自善[1] 

机构地区：[1]珠海经济特区裕华聚酯切片厂,华中师范大学化学系

出　　处：《高分子材料科学与工程》1994年第3期134-137,共4页Polymer Materials Science & Engineering

摘　　要：采用“架桥剂”法，以马来酸酐（ＭＡＮ）为“架桥剂”，使氯化聚乙烯（ＣＰＥ）主链上接上一定数量的酸酐基团，然后利用接上去的酸酐基团与ＰＭＭＡ－ＯＨ、ＰＥＧ、ＰＰＧ、ＰＴＭＧ等反应合成了主链疏水、支链亲水或疏水的双亲性聚合物，并用ＩＲ、ＴＧ－ＤＴＡ进行了表征。In this paper, double affinity graft polymers of CPE were synthesized by means of' crosslinking agent', with maleic anhydride (MAN) acting as 'crosslinking agent', PMMA, PEG, PPG, PTMO were grafted into CPE. The graft polymers were characterized by means of IR and TG UTA.

关 键 词：氯化聚乙烯 改性 高聚物 接枝共聚 

分 类 号：O632.21[理学—高分子化学]