含酞菁功能基聚苯乙烯的光电导性能研究  

Investigation on Photoconductivity of Polystyrene Containing Phthalocyanine

作　　者：潘浦敦[1] 汪茫[1] 崔海峰 杨士林[1] 

机构地区：[1]浙江大学高分子系

出　　处：《功能高分子学报》1994年第1期8-12,共5页Journal of Functional Polymers

基　　金：国家自然科学基金;浙江大学科学基金

摘　　要：合成了新型含酞菁功能基聚苯乙烯，该聚合物具有优良的溶解性能和成膜能力，同时又有一定的光电导性，对该聚合物的染料增感研究发现结晶紫，孔雀绿对于该聚合物均有增感作用，较大幅度地提高了光电导性．采用ＥＳＲ和荧光光谱的研究表明，该聚合物的光电导机理可能是形成了电荷转移络合物．Polystyrene containing phthalocyanine copper is synthesized on the base of molecular desigment of photoconductive functional POlymers.The results show that the Polymer has excellent properties of solubility film formation and certain photoconductivity.Photoconductivity of the polymer containeng higher CuPc is better than that of the polymer containing lower CuPc. meanwhile, study on dye sensitizing of the polymer reveals that crystal violet and malachite green are dopant for the polymer, they enhance the photoconductivity. Further research by the means of ESR and fluorescence spectra shows that the photoconductive mechanism may be related to the formation of charge transfer complex(CTC)

关 键 词：光电导性 含酞氰功能基 聚苯乙烯 

分 类 号：O632.13[理学—高分子化学]