丙烯酸三苯基锡酯及其聚合物的合成和表征  

Synthesis and Characterization of Triphenyltin Acrylate and Its Polywer

作　　者：刘宝殿[1] 朱东升[1] 黄姬顺 张丙强 

机构地区：[1]东北师范大学化学系

出　　处：《合成化学》1994年第3期263-267,共5页Chinese Journal of Synthetic Chemistry

摘　　要：合成了丙烯酸三苯基锡酯及其聚合物，通过ＩＲ、￣１ＨＮＭＲ、￣（１３）ＣＮＭＲ对其结构进行了表征，推断单体中的锡原子与羰基氧原子间存在分子间的配键，锡原子的配位数是５，而聚合物没有形成锡氧配键。Triplienyltin acrylate and its polymer have been syntliesized and characterized by IR,￣1H NMR and￣(13)C NMR. The spectral data shows that triphenyltin acrylate has,an intermolecular O→Sn coordination and a pentacoordinated tin atom, while its polymer has,no O→Sn coordination becausethe bulk of molecular chain prevents it from the formation of intermolecular coOrdination through oxy-sen atom.

关 键 词：丙烯酸 苯基锡酯 聚合物 合成表征 

分 类 号：O627.4[理学—有机化学]