微环电极上线性扫描伏安法准稳态可逆波理论  

The Theory of Linear Sweep Voltammetry for the Quasi-Steady-State Reversible Wave at Ultramicroring Electrode

作　　者：金葆康[1] 张祖训[1] 

机构地区：[1]南京大学化学系,南京210008

出　　处：《化学学报》1994年第2期181-185,共5页Acta Chimica Sinica

基　　金：高等学校博士学科点专项科研基金资助项目

摘　　要：本文求得了适用于不同γ(式(6))和P(式(9))的最大电流表达式,并提出了准稳态的定量标准,还推导了微环电极上线性扫描伏安法准稳态可逆波方程式.经验证,理论和实验结果相符合.In this paper, the expression of the maxium current variation with γ and P at ultramicroring electrode for linear sweep voltammetry is presented, the rule of judgement for the quasi-steady-state reversible wave is described, and the equation of linear sweep voltammetry for the quasi-steady-state reversible wave is derived also. Experimental results are in good agreement with the theoretical.

关 键 词：扫描伏安法 微环电极 准稳态 

分 类 号：O646.54[理学—物理化学]