超微盘电极上准稳态可逆波循环伏安法理论  

The Theory of Quasi-Steaty-State Reversible Wave for Cyclic Voltammetry at Ultramicro-disk Electrode

作　　者：张祖训[1] 

机构地区：[1]南京大学化学系,南京210008

出　　处：《化学学报》1994年第3期285-289,共5页Acta Chimica Sinica

基　　金：国家自然科学基金资助的项目

摘　　要：本文提出了超微盘电极上准稳态可逆波循环伏安法理论,并对环形氧化还原波的性质进行了深入的讨论,选择K_4Fe(CN)_6·KCl体系在铂微盘电极上对理论进行验证,实验结果与理论相符合.The theory of quasi-steaty-state reversible wave for voltammetry is described. The behaviours of cyclic voltammetric wave are discussed in detail. It is verified experimentally by electro-oxidation of K4Fe(CN)6 in the pressence of KCl at ultra-micro-disk electrode. The experimental results in good agree ment with the theoretical conclusions.

关 键 词：循环伏安法 超微盘电极 准稳态 

分 类 号：O646.54[理学—物理化学]