热动力学对比进度法 Ⅳ.热导式热量计的单参数理论模型与热谱重建  

Reduced Extent Method for Thermokinetics Ⅳ. A Single-parameter Theoretical Model of a Conduction Calorimeter and Thermogram Reconstruction

作　　者：刘劲松[1] 曾宪诚[1] 邓郁[1] 田安民[1] 

机构地区：[1]四川大学化学系,成都610064

出　　处：《化学学报》1994年第7期639-645,共7页Acta Chimica Sinica

基　　金：国家自然科学基金资助的项目

摘　　要：本文建立了热导式热量计的单参数理论模型,在此基础上系统地提出了热谱重建法,并结合热动力学对比进度法,对几个化学反应体系进行了热动力学研究.实验结果验证了本文方法及其理论基础的正确性.A single-parameter theoretical model of a conduction calorimeter has been suggested, on the basis of which thermogram reconstruction method was proposed systematically. This method, combining with reduced extent method, was applied to studies on thermokinetics of some chemical reaction systems. The reliability of this method and its theoretical basis have been verified by the experimental results.

关 键 词：热动力学 热导式热量计 对比进度 

分 类 号：O642.3[理学—物理化学]