具有中心功能基的网状聚合物冠醚Ⅱ．具有硫醚侧基的网状聚合物冠醚及其铂配合物的合成  

NETWORK CROWN ETHER POLYMERS WITH FUNCTIONAL GROUP (Ⅱ) SYNTHESIS OF NETWORK POLYMERIC CROWN ETHER WITH PENDANT SULFIDE SIDE CHAIN AND ITS PLATINUM COMPLEX

作　　者：陈远荫[1] 孟令芝[1] 殷以华 段和平[1] 

机构地区：[1]武汉大学化学系

出　　处：《离子交换与吸附》1994年第3期225-229,共5页Ion Exchange and Adsorption

基　　金：自然科学基金

摘　　要：通过β－乙硫乙基环氧丙基醚与一缩二乙二醇双环氧丙基醚开环共聚，合成了网状结构单元中具有硫醚侧基的网状聚合物冠醚，或交联大环聚醚。这类聚合物与铂金属形成的配合物，是烯烃与三乙氧基硅烷硅氢加成反应的高活性催化剂。Network polymeric crown ether with pendant sulfide side chain in the network structural units has been synthesized via ring - opening copolymerization of 3-ethylthioethyl glycidyl etherand diethylene glycidyl ether. A kind of active catalyst suitable for this reaction was suggested.The title polymer was found to be a good ligand for platinum salt, and the platinum complex exhibited high catalytic activity for the hydrosilylation of olefins with triethoxysilane.

关 键 词：网状 冠醚 铂配合物 硅氢加成反应 

分 类 号：TQ426.92[化学工程]