定标粒子理论对高效液相色谱中分子间相互作用与k＇间关系的研究  

A Study on the Relationship between Intermolecular Interaction and k'with Scaled Particle Theory in High Performance Liquid Chromatography

作　　者：张维冰[1] 史景江 吴也平 

机构地区：[1]齐齐哈尔轻工学院

出　　处：《色谱》1994年第4期234-238,共5页Chinese Journal of Chromatography

摘　　要：本文以统计热力学的观点，对流动相和固定相同时采用定标粒子理论处理，得到了描述分子间相互作用与ｋ＇间定量关系的关联方程，并对该方程加以实验验证及讨论。n this paper, we processed both the stationary phase and the solvent phase using the scaled particletheory based on the statistical thermodynamics,and derived a correlative equation between the intermolecularinteraction and k'.The relationship was tested exDerimentally and discussed.

关 键 词：高效 液相色谱 定标粒子 分子作用 

分 类 号：O657.72[理学—分析化学]