马来酸酐接枝聚丙烯的研究  

A Study of Polypropylene Grafted with Maleic Anhydride

作　　者：高善娟[1] 王红[1] 

机构地区：[1]南京化工学院

出　　处：《塑料工业》1989年第4期10-13,共4页China Plastics Industry

摘　　要：本文以二甲苯为溶剂,BPO为引发剂并采用滴加引发剂的方法合成了马来酸酐(MAH)接枝PP树脂。在研制过程中,考察了引发剂用量,MAH与引发剂的配比、溶剂用量,引发剂滴加时间对PP接枝率和产率的影响,结果表明,接枝率随引发剂用量的增加而相应提高,因此可以通过控制引发剂用量来控制接枝率,引发剂用量对产率影响不大;随MAH/BPO比例的增加,接枝率有增加的趋势,但产率有明显下降;溶剂用量对接枝率无大影响,但产率随溶剂用量增加而降低;随引发剂滴加时间的延长,接枝率有明显提高,而产率无明显变化。Polypropylene, grafted with maleic anhydride (MAH) was prepared by solution polymerization. Influence of the factors, such as the amount of initiating agent BPO, the proportion of MAH to BPO, the amount of solvent, and the adding time of BPO, on the grafting efficiency of PP and the conversion percentage of the products were examined. This procedure is a modification of the old one and is suitable for the preparation of PP grafted with MAH which is applicable for scientific research work.

关 键 词：马来酸酐 溶液法 接枝聚丙烯 

分 类 号：O632.12[理学—高分子化学]