谱-空间2D ESR成像  

Spectral-Spatial Two-Dimensional ESR Imaging

作　　者：郑莹光[1] 许静[2] 董凤霞[1] 沈尔中[3] 徐玉书[2] 

机构地区：[1]吉林大学测试科学实验中心,吉林长春130023 [2]吉林大学原子与分子物理所,吉林长春130023 [3]吉林大学理化所,吉林长春130023

出　　处：《波谱学杂志》2005年第1期27-33,共7页Chinese Journal of Magnetic Resonance

基　　金：国家自然科学基金资助项目(29935060).

摘　　要：在Bruker ER 200D ESR 谱仪上安装一套自制的谱 空间 2D ESR成像系统, 这套系统由一对梯度场线圈、电源、微机及图像重建程序组成. 用滤波反投影图像重建方法, 实现了两种自由基样品的谱 空间2D ESR成像, 由2D 图像得到样品中自由基的自旋密度空间分布及相应的波谱参数. 讨论了成像参数与图像精度的关系.A spectral-spatial 2D ESR imaging system was installed on a Bruker ER 200 D ESR spectrometer It consists of a pair of field gradient coils, power supplies and a computer system used for image reconstruction Spectral-spatial 2D ESR imaging was performed on several free radical samples using the filtered back-projection method The spatial distribution of the spin densities of the free radicals and the corresponding spectral parameters were acquired simultaneously from the 2D images The relationship between the imaging parameters and the accuracy of the images was discussed

关 键 词：自由基 ESR谱 成像参数 ER 梯度场 谱仪 波谱 自旋密度 场线 谱参数 

分 类 号：O442[理学—电磁学] R445.2[理学—物理]