CO气相合成草酸二乙酯的载体研究  

Carriers for Carbon Monoxide Gaseous-Phase Catalytic Reaction

作　　者：王保伟[1] 马新宾[1] 韩森[1] 许根慧[1] 

机构地区：[1]天津大学化工学院绿色合成与转化教育部重点实验室,天津300072

出　　处：《天然气化工—C1化学与化工》2005年第1期6-10,共5页Natural Gas Chemical Industry

基　　金：国家"九五"重点科技攻关项目 (96 - 5 39- 0 1)

摘　　要：考察了不同类型和经不同温度处理的Al2 O3 载体对CO气相催化偶联制备草酸二乙酯反应的影响。研究了Al2 O3载体的比表面、孔容、孔分布、晶相和强度因素对催化剂性能的影响。结果表明 ,焙烧后Al2 O3 载体的比表面积和孔容减小 ,载体的强度增大 ;载体的比表面和孔结构影响催化剂的活性 ,在合适的孔径范围内 。This study put the emphasis on the effects of different type Al_2O_3 carriers and Al_2O_3 carriers treated under different calcination temperature on the synthesis of diethyl oxalate in gaseous phase. The influences of specific surface, pore volume, pore distribution, crystal phase and strength on the function of catalysts were investigated. The results indicated that the specific surface and the pore volume decreased but the strength increased after Al_2O_3 carriers being calcined, the specific surface and the pore structure influenced the activity of catalysts, and the conversion of carbon monoxide decreased with the specific surface and the pore volume decreased under appropriate pore radius.

关 键 词：CO 载体 比表面 孔结构 强度 

分 类 号：TQ032.41[化学工程]