单取代苯丙氨基酸卟啉配合物的催化性质研究  

STUDIES ON CATALYTIC PROPERTIES OF MONOSUBSTITUTED PHENYLALANINE TETRAPHENYLPORPHYRIN AND ITS COMPLEXES

作　　者：倪春林[1] 王静秋[1] 贾密英[1] 秦子斌[1] 

机构地区：[1]武汉大学化学系

出　　处：《无机化学学报》1994年第3期317-320,共4页Chinese Journal of Inorganic Chemistry

摘　　要：初步研究了标题卟啉（Ｈ２Ｐ）及其三种配合物ＭＰ（Ｃｌ）［Ｍ＝Ｆｅ（Ⅲ）、Ｃｏ（Ⅱ）和Ｍｎ（Ⅲ）］存在下，用氧气氧化芳醛的催化吸氧动力学曲线．实验发现除Ｈ２Ｐ外，三种配合物ＭＰ（Ｃｌ）对芳醛的氧化均具有催化作用，其最高吸氧速度按ＭｎＰＣｌ＜ＣｏＰ＜ＦｅＰＣｌ顺序增大，诱导现以ＦｅＰＣｌ＞ＭｎＰＣｌ＞ＣｏＰ顺序减短，还研究了底物、ＭＰ（Ｃｌ）在反应体系中的浓度及溶剂等因素对催化氧化反应的影响．The oxidation of aromatic aldehydes with O2 has been investigated in the presence ofMP(Cl).The oxygen uptake volume of MP(Cl) during the course of the reaction was measured.It was observed the complexes can all catalyze the oxidation of aromatic aldehydes,while H2P isinactive.The order of O2 maximum uptaking rates arc MnPCl < CoP<FePCl.On the otherhand it was studied that the effect of mctalloporphyrin concentration,temperature,solvent andsubstrate on oxidation of aromatic aldchydes.

关 键 词：苯丙氨基酸 卟啉 络合物 催化氧化 

分 类 号：O643.36[理学—物理化学]