A Convenient Method for Chlorination in Allylic Position  

作　　者：WANGXin-yan SHIHong-chang CHENGang HONGXiao-yin XUShou-yi 

机构地区：[1]DepartmentofChemistry,TsinghuaUniversity,Beijing100084,P.R.China

出　　处：《Chemical Research in Chinese Universities》2005年第2期169-171,共3页高等学校化学研究（英文版）

摘　　要：A convenient method for the chlorination in allylic position was developed by using the aqueous solution of sodium hypochlorite(2%_5% active chlorine) and an acid as chlorination reagent in a diphase system. The method has the advantage of cheap reagents, mild reaction conditions and good yields. The quantity and the feeding rate of the chlorination reagent can be controlled easily. The method is particularly suitable for the chlorination in laboratories.A convenient method for the chlorination in allylic position was developed by using the aqueous solution of sodium hypochlorite(2%_5% active chlorine) and an acid as chlorination reagent in a diphase system. The method has the advantage of cheap reagents, mild reaction conditions and good yields. The quantity and the feeding rate of the chlorination reagent can be controlled easily. The method is particularly suitable for the chlorination in laboratories.

关 键 词：CHLORINATION Allylic position Sodium hypochlorite Diphase system 

分 类 号：TE626.88[石油与天然气工程—油气加工工程] O613.42[理学—无机化学]