稀土Nd、Eu氯化物与4＇，5＇－二溴苯并15－冠－5固体配合物的合成及性质  

Synthesis and Properties of Solid Coordination Compounds of Rare Earth Chlorides with 4',5'-Dibromobenzo-15-Crown-5

作　　者：耿志远[1] 董文魁[1] 卢爱茹 张联祥[1] 

机构地区：[1]兰州铁道学院,西北师范大学化学系

出　　处：《西北师范大学学报（自然科学版）》1994年第1期48-50,共3页Journal of Northwest Normal University(Natural Science)

摘　　要：以无水乙腈为溶剂，合成了Ｎｄ、Ｅｕ氯化物与４＇，５＇－二溴苯并１５－冠－５的固体配合物，进行了元素分析、红外先谱、紫外光谱及在尔电导的测定；结果表明配合物的组成为１：２型电解质．Solid coordination compounds of rare earth chlorides with 4',5'- dibromobenzo-15-crown-5have been sgnthesized in acetonitrile. They are characterized by elementary analyses,IR,UV and mea-surement of molar conductivity。 It is concluded that these complexes are 1: 2 type, hydrated eletrolyte.

关 键 词：稀土族 氯化物 络合物 冠醚 

分 类 号：O614.33[理学—无机化学]