Pd/C催化有机锡试剂和酰氯偶联反应的研究  

Study on the coupling reaction of organotins and acid chlorides catalyzed by Pd/C

作　　者：吴春[1] 李健[1] 李葵 

机构地区：[1]哈尔滨商业大学化学中心,黑龙江哈尔滨150076 [2]黑龙江省育达药业公司,黑龙江哈尔滨150076

出　　处：《化学试剂》2004年第6期361-362,375,共3页Chemical Reagents

基　　金：黑龙江省自然科学基金 (B0 1 0 5 )资助项目

摘　　要：制备了活性炭负载钯催化剂 ,并用于有机锡试剂与取代肉桂酰氯交叉偶联合成查耳酮化合物的反应中。考察了催化剂的催化性能 ,用XPS方法对催化剂进行了表征 ,还对反应机理进行了研究和探讨。The active carbon-supported palladium catalyst was prepared.The crosscoupling reaction of organotins with substituted cinnamoyl chlorides catalyzed by Pd/C for synthesis of chalcones was studied.The catalytic activity of Pd/C and the catalytic mechanism were also studied by XPS.The metallic Pd may be the active center for the coupling reaction.

关 键 词：活性炭负载钯 有机锡试剂 酰氯化合物 偶联反应 

分 类 号：O643.3[理学—物理化学]