D-葡萄糖缩水杨酰肼锌(Ⅱ)配合物的合成与结构表征  

Synthesis and Characterization of Zinc(Ⅱ) Complex of D-Glucose Salicyloyl Condensed with Hydrazine

作　　者：郭应臣[1] 卓立宏[1] 乔占平[1] 

机构地区：[1]南阳师范学院化学系,河南南阳473061

出　　处：《化学研究》2005年第1期12-14,38,共4页Chemical Research

基　　金：河南省教育厅基金资助项目(20021500008).

摘　　要：D 葡萄糖缩水杨酰肼Schiff碱与醋酸锌通过固相反应合成了D 葡萄糖缩水杨酰肼合锌(Ⅱ) [Zn(C13H17N2O7 )2 ]配合物.用元素分析,MS,UV,IR,1HNMR和TGA DTA进行了结构表征.研究表明锌离子是通过酰胺基氮和酚羟基氧参与配位,形成四配位的配合物.X射线粉末衍射指标化,确定该配合物为单斜晶系,晶胞参数为:a=0. 970 9nm,b=2. 080 6nm,c=1. 279 8nm,β=92. 45°.Zinc(Ⅱ) complex of D-glucose salicyloyl condensed with hydrazine \[Zn(C_(13)H_(17)N_2O_(7))_2\] wassynthesized by the solid-phase reaction of D-glucose salicyloy1 hydrazine Schiff base and zinc acetate.The product was characterized by elemental analysis,MS,UV,IR,~1H NMR and TGA-DTA. In the complex,the Natom of amidogenand Oatom of phenolcoordinate directly to the zincion .X-ray powder diffraction pattern indicates that the crystal structure belongs to monoclinic system.The lattice constants are: a=0.970 9 nm,b=2.080 6 nm,c=1.279 8 nm,β=92.45°.

关 键 词：D-葡萄糖缩水杨酰肼 锌配合物 XRD谱 西佛碱 化学结构 生物活性 

分 类 号：O627.23[理学—有机化学] O641.4[理学—化学]