氰酸酯/环氧树脂体系的研究  

Study on mechanical properties and dielectric properties of cyanate/epoxy resin system

作　　者：杨洁颖[1] 梁国正[1] 任鹏刚[1] 王结良[1] 房红强[1] 宫兆合[1] 

机构地区：[1]西北工业大学化学工程系,陕西西安710072

出　　处：《航空材料学报》2004年第3期21-25,共5页Journal of Aeronautical Materials

基　　金：国家自然科学基金资助项目(50273029);西北工业大学研究生创业种子基金资助项目(Z20030099)

摘　　要：采用环氧树脂(E 51)与氰酸酯树脂共聚以改善氰酸酯树脂的韧性,研究了环氧树脂的加入量、后处理温度、湿热老化、紫外光老化等条件对改性后树脂体系的力学性能和介电性能的影响规律,采用扫描电子显微镜对断口形貌进行了分析。结果表明环氧树脂可以明显改善氰酸酯树脂的韧性,环氧树脂含量为30wt%的体系的冲击强度和弯曲强度分别比改性前提高了100%和50%。随环氧树脂用量的增加,改性树脂的冲击强度和弯曲强度增大,树脂表现为明显的韧性断裂;改性体系经200℃后处理2h的介电性能最佳,环氧树脂用量的增加、湿热老化和紫外光老化都使介电常数和介电损耗增加,但当环氧树脂用量低于30wt%时仍属于优异的介电材料。Epoxy resin (E-51) was used to improve mechanical properties of cyanate ester resin by copolymerization with bisphenol A dicyanate ester. The influence of epoxy resin concentration, post cure temperature, hydrothermal aging and ultraviolet radiation aging on mechanical properties and dielectric properties of modified system was studied. The fracture surfaces of the broken specimens were examined by scanning microscopy (SEM). The modified system showed much higher fracture toughness. Inclusion of 30 wt% epoxy resin led to 100% and 50% increase in the impact strength and flexural strength, respectively. The impact strength and flexural strength were found to increase with enhanced concentration of epoxy resin, and modified resin system put up typical toughness rupture. The resin system possessed the best dielectric properties after post cure for 2 h at 200°C. Addition of epoxy resin concentration, hydrothermal aging and ultraviolet radiation aging caused increase of the dielectric constant and dielectric loss. However, the modified system belongs to excellent dielectric material, with epoxy resin concentration below 30 wt%.

关 键 词：环氧树脂体系 改性树脂 氰酸酯树脂 冲击强度 加入量 弯曲强度 介电性能 湿热老化 断口形貌 韧性 

分 类 号：V255.1[一般工业技术—材料科学与工程] TQ323[航空宇航科学与技术—航空宇航制造工程]