过渡金属与二取代冠醚固态配合物的制备  

Synthesis of Solid Complexes of Disubstituted Benzo Crown Ethers with Transition Metals

作　　者：卢爱茹 张有明[1] 张联祥[1] 戴玉杰[1] 

机构地区：[1]西北师范大学化学系,河北医学院药学系

出　　处：《应用化学》1994年第2期35-39,共5页Chinese Journal of Applied Chemistry

摘　　要：由４＇，５＇－二碘苯并１５冠５，４＇，５＇－二溴苯并１５冠５，４＇－溴－５＇－硝基苯并１５冠５，四溴二苯并１８冠６与过渡全属Ｍｎ（Ⅱ）、Ｃｏ（Ⅱ）、Ｃｕ（Ⅱ）、Ｚｎ（Ⅱ）、Ａｇ（Ⅱ）、Ｃｄ（Ⅱ）的硝酸盐、高氯酸盐、气化物合成了１９个未见报道的固态配合物。用元素分析、红外光谱、摩尔电导和差热－热重分析等表征了它们的组成和性质。Ninefeen solid complexes of4',5'-diiodobenzo-15-crown-5,4',5'-dibromobenzo-15-crown-5,4'-bromo-5'-nitrobenzo-15-crown-5,and tetrabromodibenzo-18-crown-6 withnitrates,perchlorates,chlorides of Mn(Ⅱ),Co(Ⅱ),Cu(Ⅱ),Zn(Ⅱ),Ag(Ⅰ),and Cd(Ⅱ)have been synthesized Their compositions and properties have been characterized by elemen-tal analysis, thermal analysis, IR spectra,X-ray diffractionanalysis and molar conductancemeasurements.

关 键 词：过渡金属 二取代冠醚 络合物 

分 类 号：O614.8[理学—无机化学]