丙烯腈-苯乙烯共聚物水解磺化产物对泥浆的稳定作用  

STABILIZATION OF CLAY MUD BY SIMULTANEOUS HYDROLYSIS AND SULFONATION PRODUCT OF ACRYLNITRILE-STYRENE COPOLYMER

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作  者:张维邦[1] 陈水挟[1] 

机构地区:[1]中山大学材料科学研究所

出  处:《油田化学》1994年第4期292-295,共4页Oilfield Chemistry

摘  要:在实验室条件下对用丙烯腈-苯乙烯共聚物在硫酸存在下的水解磺化产物(HSAS)处理的泥浆性能进行了评定。HSAS处理的泥浆有较小的滤失性,较好的耐盐和抗高温性。The performane of a simultaneous hydrolysis and sulfonation product of acrylnitnle-styrene copolymer, HSAS,as clay drilling mud stabilizer is evaluated in laboratory.0.3-0.5% HSAS(AN:St=90:10,prepared in 96% sulfuric acid at 100℃) in fresh water mud and 0.7% HSAS in 3% NaCl mud reduce their filtrate loss at ambient temperature down to 15ml.0.3% HSAS-treated fresh water mud maintains its filtrate loss of 22ml at 60℃ after thermal aging at 180℃ over 12 hrs.This HSAS-treated fresh water mud has increasal plastic viscosity and yield stress.The influence of copolymer composition(ratio AN/St) and sulfuric acid concentration for hydrolysis/sulfonation is also investigated. Most HSAS samples are shown to be strong viscosifier.

关 键 词:丙烯腈 苯乙烯 共聚物 稳定性 钻井泥浆 

分 类 号:TE254.4[石油与天然气工程—油气井工程]

 

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