清除树脂辅助液相合成N-苯基高邻苯酞酰亚胺衍生物及其除草活性研究(英文)  

Scavenger Resin Assisted Solution-phase Synthesis of N-phenylhomoph-thalimide Derivatives and Study on Their Herbicidal Activities

作　　者：程辟[1] 任叶果[2] 黄路[2] 胡礼[2] 徐满才[1] 黄明智[2] 

机构地区：[1]湖南师范大学化学化工学院,湖南长沙410081 [2]湖南化工研究院,湖南长沙410007

出　　处：《合成化学》2005年第2期130-133,140,共5页Chinese Journal of Synthetic Chemistry

基　　金：SupportedbytheNationalNaturalScienceFoundationofChina(20372021); NaturalScienceFoundationofHunanProvince(03JJY3018)

摘　　要：通过清除树脂辅助液相合成法合成了9个N-苯基高邻苯酞酰亚胺衍生物,纯度70%～95%.其结构经1H NMR, IR, MS和元素分析确认. 初步除草活性测试表明部分化合物在150 g.ai·ha-1对苘麻、马刺苋、凹头苋等表现出除草活性.Nine N-phenylhomophthalimide derivatives with the purities of 70%~95% were synthesized via solution-phase synthesis utilizing scavenger resin. The structures were confirmed by 1H NMR , IR, MS and elemental analysis. The preliminary herbicidal tests showed that some of the compounds exhibited herbicidal activity to Abutilon avicennae, Portulaca oleracea, Amaranthus spinosus at 150 g.ai·ha -1 .

关 键 词：清除树脂 液相合成 原卟啉原氧化酶抑制剂 除草活性 

分 类 号：O621.3[理学—有机化学] O625[理学—化学]