1DTOCSY在确定化合物结构中的应用  

Application of 1D TOCSY in structure determination of organic compounds

作　　者：罗权[1] 潘燕娜[1] 韦轶[1] 邓志威[1] 

机构地区：[1]北京师范大学分析测试中心,北京100875

出　　处：《现代仪器》2005年第2期10-13,15,共5页Modern Instruments

摘　　要：本文主要是对核磁共振一维全相关实验 (1DTOCSY)在化合物结构解析中的应用进行探讨。 1DTOCSY作为NMR中一种比较新的一维实验技术 ,为糖类等化合物的结构解析带来极大的便捷 ,具有时间短、信息清晰的特点。本文以蔗糖和乙酸戊脂为样本 ,对 1DTOCSY实验中整形脉冲的选择 ,实验参数的设置进行研究 ,并尝试建立起一种利用改变混合时间辅助完成特定化合物精细结构解析的方法。In paper,one dimensional total correlation experiment(1D TOCSY)was investigated for the application of structure elucidation.1D TOCSY is a relative new NMR technique,which has draw a great attention in the study of the structure elucidation for some of compounds such as saccharides as it can provide simple and direct information.In this paper,the selection of shaped pulse and the experimental parameters were investigated with the samples of a saccharide and pentyl ethanoate.And it was tasted to elucidate the structure of some kind of compounds in detail with the variety of the mixing time

关 键 词：TOCSY 化合物结构 应用 结构解析 核磁共振 实验技术 整形脉冲 实验参数 混合时间 NMR 极大的 一维 糖类 样本 

分 类 号：O629.13[理学—有机化学] O623.52[理学—化学]