μ-氧-双[三(对氟苄基)锡]的合成、表征及晶体结构  

Synthesis, Characterization and Crystal Structures of the μ-Oxygen-Bis[Tri(p-Fluorobenzyl)tin]

作　　者：尹汉东[1] 洪敏[1] 王传华[1] 

机构地区：[1]聊城大学化学系,聊城252059

出　　处：《无机化学学报》2005年第5期713-715,共3页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.20271025);山东省自然科学基金(No.L2003B01)资助课题。

摘　　要：The μ-oxygen-bis[tri(p-fluorobenzyl)tin] was synthesized. The structure were characterized by elementary analysis, IR and 1H NMR and the crystal structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to rhombohedral with space group R, a=1.346 4(4), b=1.346 4(4), c=1.772 9(7) nm, α=90°, β=90°, γ=120°, Z=3, V=2.783 2(15) nm3, Dc=1.625 g·cm-3, μ(Mo Kα)=1.408 mm-1, S=1.088, F(000)=1 350, R1=0.027 5, wR2=0.065 9. In compound, the tin atom has a distorted tetrahedral coordination configuration. CCDC: 257079.The μ-oxygen-bis[tri(p-fluorobenzyl)tin] was synthesized. The structure were characterized by elementary analysis, IR and 1H NMR and the crystal structure were determined by X-ray single crystal diffraction. The crystal of the title compound belongs to rhombohedral with space group R, a=1.346 4(4), b=1.346 4(4), c=1.772 9(7) nm, α=90°, β=90°, γ=120°, Z=3, V=2.783 2(15) nm3, Dc=1.625 g·cm-3, μ(Mo Kα)=1.408 mm-1, S=1.088, F(000)=1 350, R1=0.027 5, wR2=0.065 9. In compound, the tin atom has a distorted tetrahedral coordination configuration. CCDC: 257079.

关 键 词：晶体结构 crystal analysis 合成 苄基 表征 space group The the with ATOM and 锡 氟 氧 was ^1H NMR tin IR 

分 类 号：O614.121[理学—无机化学] TN915.07[理学—化学]