Grignard方法合成高分子硒化合物研究  

Study on the Synthesis of Selenium Polymer by Grignard Method

作　　者：毛豫兰[1] 黄可知[1] 龚云[1] 

机构地区：[1]武汉理工大学硅酸盐材料工程教育部重点实验室,武汉430070

出　　处：《武汉理工大学学报》2005年第4期19-22,共4页Journal of Wuhan University of Technology

摘　　要：以二卤代烷和二卤代芳烃为主要原料,采用Grignard方法合成出了脂肪族和芳香族高分子硒化合物。研究了催化剂、溶剂、卤代烃活性以及加料顺序等因素对合成反应的影响。Aliphatic and anumatic selenium polymers were synthesized with saturated dihalide and dihalogenated arene as major material by Grignard method. The effects of several factors on synthesizing reaction were studied, such as catalyst, activity of halohydrocablon, mixing order, etc. The mechanism of synthesizing reaction was researched preliminaryly.

关 键 词：高分子硒 合成 Grignard方法 

分 类 号：O63[理学—高分子化学]