空气中苯系物时间加权平均浓度测定方法  

Study on determination of time-weighted average concentration for benzene,toluene and xylenes in air

作　　者：梅勇[1] 袁鹏[1] 杨磊[2] 马晓钟[1] 许斌[1] 

机构地区：[1]东风汽车公司职业病防治研究所,湖北十堰442000 [2]华中科技大学同济医学院公共卫生学院

出　　处：《中国公共卫生》2005年第2期194-196,共3页Chinese Journal of Public Health

基　　金：卫生标准课题基金资助 (3 - 99- 751 )

摘　　要：目的　建立工作场所空气中苯系物的时间加权平均浓度 (TWA)气相色谱测定方法。方法　通过活性炭管采样 ,溶剂解吸气相色谱法测定空气中苯、甲苯、二甲苯。结果　方法线性范围分别为苯 2 0～ 5 0 μg/ml,甲苯3 1～ 1 0 0 μg/ml,二甲苯 8 5～ 6 0 0 μg/ml。相关系数介于0 9995～ 0 9999之间。检出限分别为苯 2 0 μg/ml,甲苯 3 1μg/ml,二甲苯 8 5 μg/ml;每 1 0 0mg活性炭对苯、甲苯、二甲本的穿透容量分别为 33 3,2 9 1 ,2 7 2mg。样品在活性炭管中稳定至少可保存 7d ,方法重现性好。结论　此方法的各项指标均达到了工作场所空气中毒物检测方法研制规范的要求 ,适用于工作场所空气中苯、甲苯、二甲苯的时间加权平均浓度测定。Objective To establish a gas chromatographic method with carbon disulfide desorption for benzene,toluene and xylenes in time-weighted average(TWA)concentration in the workplace air. Methods Solvents such as benzene,toluene and xylenes were sampled with charcoal tube.Solvent desorption with carbon disulfide and analysis by GC(FID)were performed.Results Linear limits of the methods:benzene 2.0 to 50?μg/ml,toluene 3.1 to 100?μg/ml and xylenes 8.5 to 600?μg/ml.The coefficient of correlation ranged from 0.999?5 to 0.999?9 .Limit of detection of the solvents above were 2.0,3.1 and 8.5?μg/ml.The braakthrough capacities of 100?mg charcoal for the solvents above were 33.3,29.1 and 27.2?mg respectively.Samples could be storaged stablity at least 7 days under normal conditions.Conclusion These methods were corresponding to the Chinese guidelines of the method for determination of toxic substances in workplace air and confirmed suitable to determine the selected solvents in TWA concentration in workplace air.

关 键 词：苯系物 TWA浓度 活性炭管 溶剂解吸 气相色谱 

分 类 号：R122.1[医药卫生—环境卫生学]