一种salen镍配合物的合成与晶体结构(英文)  

Synthesis and crystal structure of a salen nickel complex

作　　者：李立军[1] 达世俊[1] 李瀛[1] 

机构地区：[1]兰州大学功能有机分子化学国家重点实验室,甘肃兰州730000

出　　处：《兰州大学学报（自然科学版）》2005年第2期46-49,共4页Journal of Lanzhou University(Natural Sciences)

基　　金：Supported by National Natural Science Foundation of China(20272062)

摘　　要：合成和表征了一种新的salen镍配合物,并报道了其单晶衍射数据.化合物4:[NiC28H20Cl2N2O2]·CH2Cl2,M=631.00,单斜,P21/c.a=1.1086(2)nm,b=1.7521(4)nm,c=1.4819(3)nm,β=105.06(3)°,Z=4.V=2.7795(10)nm3,Dc=1.508g/cm3,R1=0.0531.R2=0.1136.A new salen nickel complex was synthesized and characterized along with the single crystal X-ray diffraction analysis. Compound 4: [NiC28H20Cl2N2O2] · CH2Cl2, M=631.00, Monoclinic, P21/c, a= 1.1086(2) nm, 6=1.752 1(4) nm, c=1.481 9(3) nm, β=105.06(3)°, Z=4, V=2.7795(10) nm3, Dc=1.508g/cm3, R1=0.0531, R2=0.1136.

关 键 词：手性SALEN 镍(Ⅱ)二聚配合物 弱键作用 

分 类 号：O743.53[理学—晶体学]