超强酸促进的甲烷活化与转化研究进展  

Development of the Study on Activation and Conversion of Methane over Superacids

作　　者：张韶红[1] 黄伟[1] 

机构地区：[1]太原理工大学山西煤科学与技术重点实验室

出　　处：《天然气化工—C1化学与化工》2005年第2期44-48,54,共6页Natural Gas Chemical Industry

基　　金：山西省自然科学基金资助项目 (2 0 0 0 1 0 1 6)

摘　　要：综述了超强酸包括液体超强酸和固体超强酸在甲烷活化与转化中的研究进展,并对一些催化剂活化甲烷的方式、机理及存在的问题进行了探讨。在通过中间体途径活化甲烷的研究中,以固体超强酸负载金属的复合型催化剂是在温和条件下活化转化甲烷的很有前景的具有绿色催化反应意义的活性催化剂。The development of the application of superacids including liquid and solid superacids to activation and conversion of methane had been summarizded. Some catalytic activation way and mechanism over superacids as well as the problems existed in the study have also been discussed. By the research of methane, activation through intermediates, it is gradually convinced that the complex catalyst made of metal supported solid superacids used in the activation of methane at the mild conditions is prospective and green .

关 键 词：甲烷活化转化 液体超强酸 固体超强酸 

分 类 号：TQ203.2[化学工程—有机化工]