常温下合成磷酸三苯酯的研究  

Study on the Synthesis of Triphenyl Phosphate at Room Temperature

作　　者：靳通收[1] 刘利宾[1] 姚剑申[1] 张建设[1] 王爱卿[1] 

机构地区：[1]河北大学化学与环境科学学院,保定071002

出　　处：《有机化学》2005年第5期595-597,i005,共4页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.29872011);教育部高等学校青年骨干教师基金;河北省教育厅基金(No.990104)资助项目

摘　　要：研究了常温下由苯酚钠悬胶体与三氯氧磷反应合成磷酸三苯酯的工艺条件,找到了一条比较好的合成方法.此方法具有操作方便、条件温和、反应时间短、能耗低、腐蚀小、污染少、产物纯、产率高等优点.Some technological conditions of the synthesis of triphenyl phosphate by the reaction of sodium phenolate and phosphorus oxychloride were studied, and a better process was found out. This method provided several advantages such as easy operation, mild reaction conditions, short reaction time, low energy consumption, less corrosion, low contamination, high purity and high yield of product.

关 键 词：磷酸三苯酯 合成方法 催化剂 苯酚 苯酚钠悬胶体 摩尔配比对反应 

分 类 号：TQ265.1[化学工程—有机化工]