钼铜硫异核双金属配合物的合成与结构特征的研究  

STUDIES ON SYNTHESIS AND STRUCTURE CHARACTERIZATION OF MOLYBDENUM-COPPER-SULFUR HETERONUCLEAR BIMETALLIC COMPLEXES

作　　者：石有茂 陆世维[1] 郭和夫[1] 

机构地区：[1]中国科学院大连化学物理研究所

出　　处：《无机化学学报》1989年第2期126-128,共3页Chinese Journal of Inorganic Chemistry

基　　金：中国科学院科学基金资助的课题

摘　　要：利用新方法合成了一类新型的钼铜硫异校双金属配合物Mo(t-BuNC)_4(μ-t-BuS)_2CuX,3X=Cl,4X=Br,5X=I,其中3和5为未知的新化合物;研究了它们的IR,~1H NMR特征;考察了它们与生体内钼铜对抗作用的可能关系。In this communication we have reported ths synthesis and structure characterization of molybdenum- copper -sulfur heteronuclcar bimetallic complexes Me(t- BuNC)4 (μ- t - BuS)2 CuX ,3 X = Cl,4 X = Br and 5 X = I which were obtained by the reactions of Mo(t-BuNC)4(t-BuS)2with Cu2X2(X-Cl,Br,I). It has been studied IR and 1H NMR spectra of the complexes and examinated the possible relationship between the new Mo-Cu-S reactions and antagonistic function of molybdenum against copper in ruminants.

关 键 词：钼铜硫配合物 合成 结构 

分 类 号：O614.612[理学—无机化学]