掺Nd^(3+)玻璃微球发射光谱研究  

Photoluminescence Spectra of Trivalent Neodymium Doped TiBa Glass Microspheres

作　　者：王吉有[1] 郝伟[1] 赵丽娟[2] 陆颖[3] 

机构地区：[1]北京工业大学数理学院,北京100022 [2]南开大学物理学院光子学研究中心,天津300071 [3]天津大学精密仪器与光电子工程学院,天津300072

出　　处：《光谱学与光谱分析》2005年第4期499-501,共3页Spectroscopy and Spectral Analysis

基　　金：国家自然科学基金 (60 1 780 2 4 ;60 2 780 32 );北京工业大学博士科研启动基金资助

摘　　要：采用粉末喷烧法制备了掺Nd3 + 高折射率TiBa玻璃微球,主要成分为TiO2 ,BaO和SiO2 ,微球直径在30 μm左右。在带有显微镜的光谱仪上,用5 14nm激光照射微球的边缘,测量了它们的发射光谱,观察到了微球腔效应导致的光谱结构共振。在较低泵浦阈值(2mW )下,获得了Nd3 + 的激射发光。利用光学微腔理论讨论了玻璃微球荧光光谱中的形貌共振,实验结果与计算结果相符。In this work, TiBa glass microspheres doped with Nd3+ for morphology-dependent resonances of emission were designed and prepared. The emission spectra of TiBa glass plate and TiBa glass microspheres (45 and 13 pin in diameter) under 514 nm. excitation were measured. The authors observed many regularly spaced, sharp peaks in the emission spectra of a Nd3+-doped glass microsphere. Based on the Me scattering theory, the wavelength separation between the adjacent resonant peaks for the 45 pm sphere was calculated to be 3.0 for 810 run. This value agrees well with the observed peak separation (3.1 nm), which indicates the contribution of the whispering gallery modes. The emission intensities of a Nd3+-doped TiBa glass microsphere (13 μ m in diameter) in the 901.69 nm region were plotted against the excitation laser power. The emission intensities of the microsphere exhibit the linear dependence at the low excitation power (< 2 mW). The 901.69 nm emission intensity of the microsphere steeply increases at the excitation power of 2 mW, which can be ascribed to the laser operation.

关 键 词：掺ND^3+ 玻璃微球 光谱研究 TIBA 高折射率 TiO2 主要成分 SiO2 激光照射 发射光谱 结构共振 泵浦阈值 形貌共振 荧光光谱 光学微腔 计算结果 BaO 光谱仪 显微镜 腔效应 粉末 

分 类 号：TQ171.79[化学工程—玻璃工业] TN722.32[化学工程—硅酸盐工业]