Oxidation of Alcohols Catalyzed by Ruthenium Complexes with Iodosylbenzene as Oxidant  

作　　者：ZiQiangLEI QiaoXiangKANG XiangZhenBAI ZhiWangYANG QingHuaZHANG 

机构地区：[1]KeyLaboratoryofPolymerMaterialsofGansuProvince,CollegeofChemistryandChemicalEngineering,NorthwestNormalUniversity,Lanzhou730070

出　　处：《Chinese Chemical Letters》2005年第6期846-848,共3页中国化学快报（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(No.20174031).

摘　　要：Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinoline, Bipy=2, 2′-bipyridine) were synthesized and used as catalysts for the oxidation of benzylic and primary aliphatic alcohols with iodosylbenzene as oxidant. The oxidations were carried out at room temperature, affording the corresponding aldehydes and ketones with high selectivity.

关 键 词：ALCOHOLS catalytic oxidation ruthenium complexes iodosylbenzene. 

分 类 号：O614.821[理学—无机化学]