壳壁上具有介孔的Si/Al复合氧化物中空微球的制备  

Preparation of Hollow Spheres of Si/Al Composite Oxide with Mesopores in the Shell Wall

作　　者：姜艳秋[1] 刘艳华[1] 赵旭[1] 赵敬哲[1] 田玉美[1] 王子忱[1] 

机构地区：[1]吉林大学化学学院,长春130023

出　　处：《高等学校化学学报》2005年第6期1018-1020,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:50372025)资助

摘　　要：Hollow spheres of Si/Al composite oxide with mesopores in the shell wall were prepared by combining O/W/O emulsion with sol-gel process. In this study, TEOS and aluminum isopropylate were used as silicon resource and aluminum resource, respectively. As an additive, PEG-20000 was added into the inorganic precursors. TEM and N2 adsorption-desorption isotherms indicate the presence of mesopores with uniform pore size in the shell wall. The diameter, shell thickness and hollow structure property of the spheres were characterized by transmission polarized light microscopy and SEM. （）27Al MAS NMR spectrum shows that the coordinated number of the aluminum species is four. The influences on special morphology under different oil phase and reaction temperature were also investigated. The hollow spheres exhibit high thermal stability and can remain their intact spherical structures even after calcination at 550 ℃ for 6 h. This strategy can be extended to synthesize hollow spheres of other binary composite oxide with mesopores.Hollow spheres of Si/Al composite oxide with mesopores in the shell wall were prepared by combining O/W/O emulsion with sol-gel process. In this study, TEOS and aluminum isopropylate were used as silicon resource and aluminum resource, respectively. As an additive, PEG-20000 was added into the inorganic precursors. TEM and N_2 adsorption-desorption isotherms indicate the presence of mesopores with uniform pore size in the shell wall. The diameter, shell thickness and hollow structure property of the spheres were characterized by transmission polarized light microscopy and SEM. ()^(27)Al MAS NMR spectrum shows that the coordinated number of the aluminum species is four. The influences on special morphology under different oil phase and reaction temperature were also investigated. The hollow spheres exhibit high thermal stability and can remain their intact spherical structures even after calcination at 550 ℃ for 6 h. This strategy can be extended to synthesize hollow spheres of other binary composite oxide with mesopores.

关 键 词：中空球 复合氧化物 介孔 热稳定性 

分 类 号：O612.3[理学—无机化学]