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机构地区:[1]天津大学化工学院,天津300072 [2]中国石油天然气总公司内蒙分公司,呼和浩特010070
出 处:《化工进展》2005年第5期475-479,共5页Chemical Industry and Engineering Progress
基 金:国家自然科学基金资助项目(No 20263002)
摘 要:介绍了富氢气中CO的净化技术以及选择性催化氧化CO的必要性, 并对各类选择性氧化除去富氢气中CO催化剂的研究进展和性能进行了对比, 着重评述了各类金基催化剂的特点、反应机理和失活原因。H_2-fuelled, polymer electrolyte membrane cells (PEMFC) have caught considerable attention as a cleaner, more efficient system. Pt anodes are often poisoned by CO, so H 2rich mixtures should be essentially free of CO. Some techniques of purifying H 2rich gas were evaluated. The studies showed that preferential oxidation of CO was most straightforward and cost effective. In this work all kinds of preferential CO oxidation catalysts were reviewed. Emphasis was made on the study and development of Aubased catalysts.
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