焙烧温度对甲烷催化部分氧化Ni/MgO-Al_2O_3催化剂结构和性能的影响  

Effects of calcinations temperature on structure and catalytic performance of Ni/MgO-Al_2O_3 catalysts for partial oxidation of methane

作　　者：宫立倩[1] 陈吉祥[1] 邱业君[1] 张继炎[1] 

机构地区：[1]天津大学化工学院工业催化与工程系,天津300072

出　　处：《燃料化学学报》2005年第2期224-228,共5页Journal of Fuel Chemistry and Technology

摘　　要：采用TPR、BET、XRD、TG及反应性能评价等研究方法,考察了焙烧温度对甲烷催化部分氧化制合成气Ni/MgO-Al2O3催化剂结构和性能的影响。研究结果表明,随焙烧温度的升高, Ni/MgO-Al2O3 中的镍物种与载体作用逐渐增强,生成了NiAl2O4 尖晶石和NiMgO2 固熔体。虽然焙烧温度提高会使催化剂比表面降低,由于尖晶石结构的形成,其热稳定性会明显提高,将有利于抑制催化剂在反应过程中因烧结而失活的可能性。与低温焙烧的催化剂相比,高温焙烧的催化剂仍表现出良好催化反应性能,并具有相对较好的稳定性。高温焙烧的催化剂在反应过程中床层的热点温度相对较低,热点温度波动幅度也较小。低温和高温焙烧的Ni/MgO-Al2O3 催化剂在常压、1 083K、CH4 与O2 摩尔比为1. 8、空速2. 66×105h-1的反应条件下均具有良好的抗积炭性能。The effects of calcination temperature on the properties of Ni/MgO-Al_2O_3 were studied by the means of XRD, TPR, BET,TG and catalytic performance evaluation. With the increase of calcination temperature of the catalysts, the interaction between nickel species and support became stronger, and NiAl_2O_4, MgAl_2O_4 spinel and NiMgO_2 formed. Compared with γ-alumina, the Ni/MgO-Al_2O_3 catalysts showed larger specific surface area even at higher calcination temperature due to the formation of spinel. In the partial oxidation of methane to syngas, the Ni/MgO-Al_2O_3 catalysts calcinated at higher temperature exhibited better stability under the conditions of atmospheric pressure, 1083K, CH_4/O_2=1.8 and 2.66×10~5h^(-1). Whether Ni/MgO-Al_2O_3 catalysts were calcined at low or high temperature, they all showed higher resistance to coking. In addition, the hotspot temperature of the catalytic bed for the catalysts calcinated at high temperature decreased, which benefits to prevent the catalysts from sintering.

关 键 词：催化部分氧化 Al2O3 焙烧温度 催化剂 MGO NI 甲烷 催化反应性能 高温焙烧 反应过程 热点温度 结构和性能 A12O3 尖晶石结构 抗积炭性能 研究方法 性能评价 研究结果 热稳定性 低温焙烧 波动幅度 反应条件 TPR BET XRD 

分 类 号：O643.36[理学—物理化学] TE646[理学—化学]