两个7-氧杂-二苯芴-3,11-二磺酸镉化合物的合成、结构与荧光性质研究(英文)  

Synthesis, Structures, and Photoluminescence Studies of Two Cadmium(Ⅱ) (Complexes of 7-Oxa-dibenzofluorene-3,11-disulfonate

作　　者：郭礼荣[1] 汪波[1] 冯小龙[1] 谭民裕[2] 鲁统部[1] 

机构地区：[1]中山大学化学与化学工程学院中山大学测试中心,广州510275 [2]兰州大学化学化工学院,兰州730000

出　　处：《无机化学学报》2005年第7期987-992,共6页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金((No.20371051);广东省自然科学基金团队(No.04205405)资助项目。

摘　　要：通过使用浓硫酸对2,2'-二羟基-1,1'-二萘的磺化与成环反应得到一种新配体,7-氧杂-二苯芴-3,11-二磺酸。通过水热方法得到了它的两个化合物,[CdL(bipy)2(H2O)][Cd(bipy)2(H2O)2]·L·H2O(1)和[CdL(phen)2(H2O)]·5H2O(2),并通过X-射线单晶衍射分析进行结构表征。化合物1以P1空间群结晶,晶胞参数为a=1.2055(6),b=1.5764(8),c=1.9545(10)nm,α=75.755(9),β=88.093(10),γ=89.035(10)°。化合物2以P21/c空间群结晶,晶胞参数为a=2.1040(7),b=1.3580(4),c=1.4289(5)nm,β=94.543(6)°。在化合物1中,有两个独立的镉髤离子不对称单元,在其中镉(1)离子和两个联吡啶上的四个氮原子,磺酸配体上的一个氧原子及一个水分子配位;镉(2)离子和两个联吡啶上的四个氮原子和两个水分子配位。两种固体化合物在室温下均显示强的蓝色荧光。A new ligand, 7-oxa-dibenzofluorene-3,11-disulfonic acid (H2L), was synthesized by sulfonation and ring closure of 2,2′-dihydroxyl-1,1′-binaphthalene with concentrated sulfuric acid. Its two complexes, [CdL(bipy)2(H2O)][Cd(bipy)2(H2O)2]·L·H2O (1) (bipy=2,2(-bipyridyl) and [CdL(phen)2(H2O)]·5H2O (2) (phen=1,10-phenanthroline), were obtained by a hydrothermal route, and structurally characterized by X-ray single-crystal diffraction. Compound 1 crystallized in space group P1 with cell parameters a=1.205 5(6), b=1.576 4(8), c=1.954 5(10) nm, α=75.755(9), β=88.093(10), and γ=89.035(10)°. In 1, there are two independent Cd( ions in the asymmetric unit, in which one Cd(1) ion is coordinated with four nitrogen atoms from two bipy molecules, one oxygen atom of L2- anion, and one water molecule; the Cd(2) ion is coordinated with four bipyridyl nitrogen atoms and two water molecule. Compound 2 crystallized in space group P21 / c with cell parameters a=2.104 0(7), b=1.358 0(4), c=1.428 9(5) nm, and β=94.543(6)°. In 2, the coordination environment of Cd( ion is similar to that of Cd(1) ion in 1, producing a mononuclear unit. Both compounds exhibit strong blue photoluminescence in the solid state at room temperature. CCDC: 1, 258028; 2, 258029.

关 键 词：7-氧杂-二苯芴-3 11-二磺酸 镉配合物 合成 晶体结构 荧光性质 

分 类 号：O614.242[理学—无机化学] O641.4[理学—化学]